Silicon Basics Cheat Sheet

1. General Information

  • Symbol: Si
  • Atomic Number: 14
  • Atomic Mass: 28.09 u
  • Group: 14 (Carbon Group)
  • Period: 3
  • Block: p-block
  • Electron Configuration: 1s² 2s² 2p⁶ 3s² 3p²
  • Valence Electrons: 4
  • Phase at Room Temperature: Solid

2. Isotopes of Silicon

Isotope Protons Neutrons Abundance Notes
²⁸Si 14 14 92.23% Most abundant.
²⁹Si 14 15 4.67% Stable.
³⁰Si 14 16 3.1% Stable.

3. Physical Properties

  • Color: Gray with metallic luster
  • Odor: Odorless
  • Density: 2.33 g/cm³
  • Melting Point: 1,414°C
  • Boiling Point: 3,265°C
  • State at STP: Solid
  • Hardness: Brittle, crystalline structure (like glass).

4. Chemical Properties

  • Moderately Reactive:
    • Forms silicon dioxide (SiO₂) in air.
    • Resists corrosion by water and acids but reacts with halogens.
  • Forms Covalent Bonds:
    • Tetravalent (can form four bonds).
  • Semiconductor Properties:
    • Conducts electricity better than non-metals but worse than metals.

Reaction with Oxygen (Oxidation):

Si + O₂ → SiO₂ (Silicon Dioxide)  

Reaction with Hydrofluoric Acid:

SiO₂ + 6HF → H₂SiF₆ + 2H₂O  

5. Occurrence and Abundance

  • Second most abundant element in Earth’s crust (after oxygen).
  • Found in:
    • Rocks and Sand: Quartz, granite, feldspar.
    • Silicates: Form the majority of Earth’s minerals.
  • Not found in Free State: Always in compounds (e.g., SiO₂).

6. Industrial Production of Silicon

  • Extracted from Quartz (SiO₂):
    SiO₂ + 2C → Si + 2CO (Reduction with carbon in electric arc furnaces)  
    
  • Refined Further for Electronics:
    • Zone Refining: Produces ultra-pure silicon.

7. Uses of Silicon

Application Description
Semiconductors Microchips, transistors, solar cells.
Construction Concrete, glass, and bricks.
Alloys Aluminium-silicon alloys for automotive parts.
Cosmetics and Sealants Silicone-based products.
Glass and Ceramics Silica (SiO₂) used in glassmaking.
Aerospace and Defense High-strength silicon carbide (SiC).
Medical Implants Silicone for surgical implants.

8. Important Silicon Compounds

Compound Formula Use
Silicon Dioxide SiO₂ Glass, sand, concrete.
Silicones (R₂SiO)n Lubricants, sealants, medical devices.
Silicon Carbide SiC Abrasives, cutting tools.
Silicon Tetrachloride SiCl₄ Optical fibers, semiconductors.
Sodium Silicate Na₂SiO₃ Detergents, water treatment.

9. Biological Importance of Silicon

  • Trace Element in Humans and Plants:
    • Supports bone strength and connective tissue.
    • Promotes plant growth and cell wall strength.
  • Essential for Diatoms: Microscopic algae use silica to form protective shells.

10. Silicon in Technology

  • Key Material in Electronics:
    • Used in transistors and microchips for computers and phones.
  • Solar Panels:
    • Photovoltaic cells are made from silicon wafers.
  • Silicon Valley:
    • Named after the use of silicon in the tech industry.

11. Environmental Role of Silicon

  • Rock Cycle:
    • Forms minerals that shape Earth’s crust and geological processes.
  • Silica Dust:
    • Can cause lung diseases (silicosis) if inhaled.
  • Sustainable and Abundant:
    • Silicon-based materials are widely recyclable.

12. Safety and Hazards

  • Inert in Pure Form:
    • Does not pose direct health risks.
  • Silica Dust (SiO₂):
    • Prolonged exposure can lead to respiratory issues.
  • Silicon Compounds:
    • Some are corrosive (e.g., SiCl₄ reacts with moisture to form HCl).

Handling Precautions:

  • Ventilation when working with silica dust.
  • Use respirators and safety goggles during cutting or grinding.

Fun Facts About Silicon:

  • Named after the Latin word “silex” meaning flint or hard stone.
  • Silicon makes up 27% of Earth’s crust.
  • Silicon-based life forms are a common science fiction trope!
  • The first transistor was made from silicon and germanium.

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